author ="Pham, Tony and Forrest, Katherine A. and Falcao, Eduardo H. L. and Eckert, Juergen and Space, Brian",
title  ="Exceptional H2 sorption characteristics in a Mg2+-based metal-organic framework with small pores: insights from experimental and theoretical studies",
journal  ="Phys. Chem. Chem. Phys.",
year  ="2016",
volume  ="18",
issue  ="3",
pages  ="1786-1796",
publisher  ="The Royal Society of Chemistry",
doi  ="10.1039/C5CP05906B",
url  ="http://dx.doi.org/10.1039/C5CP05906B",
abstract  ="Experimental sorption measurements{,} inelastic neutron scattering (INS){,} and theoretical studies of H2 sorption were performed in [small alpha]-[Mg3(O2CH)6]{,} a metal-organic framework (MOF) that consists of a network of Mg2+ ions coordinated to formate ligands. The experimental H2 uptake at 77 K and 1.0 atm was observed to be 0.96 wt%{,} which is quite impressive for a Mg2+-based MOF that has a BET surface area of only 150 m2 g-1. Due to the presence of small pore sizes in the MOF{,} the isosteric heat of adsorption (Qst) value was observed to be reasonably high for a material with no open-metal sites (ca. 7.0 kJ mol-1). The INS spectra for H2 in [small alpha]-[Mg3(O2CH)6] is very unusual for a porous material{,} as there exist several different peaks that occur below 10 meV. Simulations of H2 sorption in [small alpha]-[Mg3(O2CH)6] revealed that the H2 molecules sorbed at three principal locations within the small pores of the framework. It was discovered through the simulations and two-dimensional quantum rotation calculations that different groups of peaks correspond to particular sorption sites in the material. However{,} for H2 sorbed at a specific site{,} it was observed that differences in the positions and angular orientations led to distinctions in the rotational tunnelling transitions; this led to a total of eight identified sites. An extremely high rotational barrier was calculated for H2 sorbed at the most favorable site in [small alpha]-[Mg3(O2CH)6] (81.59 meV); this value is in close agreement to that determined using an empirical phenomenological model (75.71 meV). This rotational barrier for H2 exceeds those for various MOFs that contain open-metal sites and is currently the highest yet for a neutral MOF. This study highlights the synergy between experiment and theory to extract useful and important atomic level details on the remarkable sorption mechanism for H2 in a MOF with small pore sizes."}