@Article{Nugent2013, author ="Nugent, Patrick and Rhodus, Vanessah and Pham, Tony and Tudor, Brant and Forrest, Katherine and Wojtas, Lukasz and Space, Brian and Zaworotko, Michael", title ="Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution", journal ="Chem. Commun.", year ="2013", volume ="49", issue ="16", pages ="1606-1608", publisher ="The Royal Society of Chemistry", doi ="10.1039/C3CC37695H", url ="http://dx.doi.org/10.1039/C3CC37695H", abstract ="Pillar substitution in a long-known metal-organic material with saturated metal centres{,} [Cu(bipy)2(SiF6)]n{,} has afforded the first crystallographically characterized porous materials based upon TiF62- and SnF62- anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2vs. CH4 and N2."}