@Article{C5CC05866J, author ="Scott, Hayley S. and Bajpai, Alankriti and Chen, Kai-Jie and Pham, Tony and Space, Brian and Perry, John J. and Zaworotko, Michael J.", title ="Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1{,}2-bis(4-pyridyl)acetylene)2(Cr2O7)]n", journal ="Chem. Commun.", year ="2015", volume ="51", issue ="80", pages ="14832-14835", publisher ="The Royal Society of Chemistry", doi ="10.1039/C5CC05866J", url ="http://dx.doi.org/10.1039/C5CC05866J", abstract ="A primitive cubic (pcu) network of formula [Ni(1{,}2-bis(4-pyridyl)acetylene)2(Cr2O7)]n{,} DICRO-2-Ni-i{,} has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Qst) of 30.5 kJ mol-1 towards CO2 at zero loading. Qst is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials{,} a feature that can be understood after studying pore structure and molecular simulations of CO2 adsorption."}